Global Warming Potential
The global warming potential (GWP) depends on both the efficiency of the molecule as a greenhouse gas and its atmospheric lifetime. GWP is measured relative to the same mass of CO2 and evaluated for a specific timescale. Thus, if a molecule has a high GWP on a short time scale (say 20 years) but has only a short lifetime, it will have a large GWP on a 20 year scale but a small one on a 100 year scale. Conversely, if a molecule has a longer atmospheric lifetime than CO2 its GWP will increase with time.
Examples of the atmospheric lifetime and GWP for several greenhouse gases include:
- Carbon dioxide has a variable atmospheric lifetime, and cannot be specified precisely. Recent work indicates that recovery from a large input of atmospheric CO2 from burning fossil fuels will result in an effective lifetime of tens of thousands of years. Carbon dioxide is defined to have a GWP of 1 over all time periods.
- Methane has an atmospheric lifetime of 12 ± 3 years and a GWP of 72 over 20 years, 25 over 100 years and 7.6 over 500 years. The decrease in GWP at longer times is because methane is degraded to water and CO2 through chemical reactions in the atmosphere.
- Nitrous oxide has an atmospheric lifetime of 114 years and a GWP of 289 over 20 years, 298 over 100 years and 153 over 500 years.
- CFC-12 has an atmospheric lifetime of 100 years and a GWP of 11000 over 20 years, 10900 over 100 years and 5200 over 500 years.
- HCFC-22 has an atmospheric lifetime of 12 years and a GWP of 5160 over 20 years, 1810 over 100 years and 549 over 500 years.
- Tetrafluoromethane has an atmospheric lifetime of 50,000 years and a GWP of 5210 over 20 years, 7390 over 100 years and 11200 over 500 years.
- Sulphur hexafluoride has an atmospheric lifetime of 3,200 years and a GWP of 16300 over 20 years, 22800 over 100 years and 32600 over 500 years.
- Nitrogen trifluoride has an atmospheric lifetime of 740 years and a GWP of 12300 over 20 years, 17200 over 100 years and 20700 over 500 years.
Source: IPCC Fourth Assessment Report, Table 2.14. |
